Preparation and Characterization of High- Viscosity Montmorillonite

被引:3
|
作者
Wu, Limei [1 ]
Wang, Xiaolong [2 ]
Zhao, Mingyu [1 ]
Gao, Fei [1 ]
Gao, Lili [1 ]
Lv, Guocheng [3 ]
Yin, Li [3 ]
Xu, Changwei [1 ]
机构
[1] Shenyang Jianzhu Univ, Sch Mat Sci & Engn, Shenyang 110168, Liaoning, Peoples R China
[2] Shenyang Jianzhu Univ, Procurement & Bidding Off, Shenyang 110168, Liaoning, Peoples R China
[3] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Jiangsu, Peoples R China
基金
中国博士后科学基金;
关键词
Adsorption; Montmorillonite; Organic Intercalation; Viscosity; RHEOLOGICAL PROPERTIES; CLAY-MINERALS; INTERLAYER STRUCTURE; IONIC LIQUIDS; ADSORPTION; SURFACTANT; DYNAMICS; BEHAVIOR; MICROSTRUCTURE; INTERCALATION;
D O I
10.1007/s42860-019-00024-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrophobicity, high viscosity, and dispersion are important properties for organo-montmorillonites, and all organo-montmorillonite configurations have yet to be fully characterized with respect to this property. High-viscosity montmorillonite (Mnt) is useful in gels and as an adsorber. The current study focused on modifying Mnt using organic cations and anions of various chain lengths in batch experiments with various concentrations and ratios. The viscosity of organic Mnt reached up to 395 mP.s. Molecular dynamics simulations and X-ray diffraction (XRD) were used to identify the conditions and arrangement of organic cations and anions in the Mnt interlayer area. The intercalation mechanism of organic cations and anions was also determined, providing a theoretical basis for the preparation of high-viscosity Mnt.
引用
收藏
页码:306 / 314
页数:9
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