Catalytic carbonylation methods without the direct use of carbon monoxide

被引：3

作者：

Morimoto, T ^{[1
]}

Fuji, K ^{[1
]}

Kakiuchi, K ^{[1
]}

机构：

[1] NAIST, Grad Sch Mat Sci, Nara 6300192, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2004年 / 62卷 / 09期

关键词：

carbonylation; carbon monoxide; formates; formamides; formic acid; chloroform; aldehydes; metal carbonyls; carbamoylsilane;

D O I：

10.5059/yukigoseikyokaishi.62.861

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbonylation chemistry (carbon monoxide chemistry) has been the subject of extensive research in labo-scale organic syntheses as well as industrial processes, since it provides a powerful tool for the direct synthesis of a wide variety of carbonyl-containing compounds. However, the methods suffer from major disadvantages, including the high toxicity of carbon monoxide and difficulties in handling this gaseous reagent. The review describes innovative strategies to solve these drawbacks. The strategies should provide many synthetic organic chemists with experimentally simple and safe tools for carbonylation.

引用

页码：861 / 871

页数：11

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