Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)

被引：2
|
作者：
Sun, Jingya [1 ]
Tong, Xiangdi [1 ]
机构：
[1] Zhejiang Ocean Univ, Coll Marine Sci, Zhoushan 316000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S160053680905346X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Cu(C12H6N2O5)(H2O)], the Cu-II ion is in a slightly distorted square-pyramidal coordination environment with two N and two O atoms from a 6,6'-oxydipicolinate ligand occupying the basal plane and a water ligand in the apical site. The dihedral angle between the two pyridine rings is 5.51 (6)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link molecules into a two-dimensional network. In addition, weak intermolecular C-H center dot center dot center dot O and C=O(lone pair)center dot center dot center dot pi(ring) interactions, with O center dot center dot center dot ring-centroid distances of 3.697 ( 4) and 3.094 ( 4) angstrom, provide additional stabilization.
引用
收藏
页码：M70 / U755
页数：10
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