Narcissistic self-sorting in anion-coordination-driven assemblies

被引：19

作者：

Zhao, Xiaotong ^{[1
]}

Wang, Heng ^{[2
]}

Li, Boyang ^{[1
]}

Zheng, Bo ^{[1
]}

Yang, Dong ^{[1
]}

Xu, Wenhua ^{[1
]}

Li, Xiaopeng ^{[2
]}

Yang, Xiao-Juan ^{[1
]}

Wu, Biao ^{[1
]}

机构：

[1] Northwest Univ, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Peoples R China

[2] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518055, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 49期

基金：

中国国家自然科学基金;

关键词：

TRIPLE HELICATE; ORGANIZATION; RECOGNITION; CAGE; COMPLEXES; SELECTION; TRANSFORMATIONS; INTERCONVERSION; ENCAPSULATION; CONSTRUCTION;

D O I：

10.1039/d1cc01652k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three tris-bis(urea) ligands with triphenylamine-based C-3-symmetric spacers were synthesized, which assembled with sulfate or phosphate to form anionic A(3)L(2) pinwheel helices (A = anion and L = ligand) and A(4)L(4) tetrahedra, respectively. Interestingly, narcissistic self-sorting was observed in both structures from the mixture of the ligands, wherein each assembly contains only one type of ligand with no detectable mixed-ligand product as confirmed by the NMR and MS studies.

引用

页码：6078 / 6081

页数：4

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