ELECTROCHEMICAL SYNTHESIS OF Fe-W NANOSTRUCTURAL ELECTROCATALYTIC COATINGS

被引：3
|
作者：
Bersirova, O. L. [1 ]
Bilyk, S. V. [1 ]
Kublanovs'kyi, V. S. [1 ]
机构：
[1] Ukrainian Natl Acad Sci, Vernadskii Inst Gen & Inorgan Chem, Kiev, Ukraine
来源：
MATERIALS SCIENCE | 2018年 / 53卷 / 05期
关键词：
Fe-W alloy; electrodeposition; coating; nanocrystalline structure; electrocatalysis; CORROSION PROPERTIES; SILVER COATINGS; ALLOYS; ELECTRODEPOSITION; MOLYBDENUM; TUNGSTEN;
D O I：
10.1007/s11003-018-0130-2
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Electrolytic Fe-W alloys are synthesized from citrate-ammonia electrolytes at current densities of 1-10 A. dm(-2) when their chemical composition undergoes insignificant changes. The structure of alloys is nanocrystalline, the block size is 20-40 angstrom, and the roughness is similar to 50-70 nm. It is shown that coatings by these alloys of the best quality can be obtained for the following optimal parameters: a current density of 1.5 A. dm(-2), pH 7.5, and a temperature of 70 degrees C. In the cyclic volt-ampere characteristic recorded in a 1 M KOH solution with an addition of ethanol, we detect a maximum of current caused by the electrooxidation of ethanol. This fact confirms the electrocatalytic properties of coatings in alkaline media.
引用
收藏
页码：732 / 738
页数：7
相关论文
共 50 条
  • [1] Electrochemical Synthesis of Fe–W Nanostructural Electrocatalytic Coatings
    О. L. Bersirova
    S. V. Bilyk
    V. S. Kublanovs’kyi
    Materials Science, 2018, 53 : 732 - 738
  • [2] Electrochemical synthesis of Fe-W and Fe-W-P magnetic amorphous films and Fe-W nanowires
    Barbano, E. P.
    Carlos, I. A.
    Valles, E.
    SURFACE & COATINGS TECHNOLOGY, 2017, 324 : 80 - 84
  • [3] Synthesis and Characterization of Fe-W and Ni-W Composite Coatings
    Chiriac, H.
    Moga, A. E.
    Gherasim, C.
    Lupu, N.
    ROMANIAN JOURNAL OF INFORMATION SCIENCE AND TECHNOLOGY, 2008, 11 (02): : 123 - 132
  • [4] Phase transformations and electrochemical characterizations of electrodeposited amorphous Fe-W coatings
    Wang, Song
    Zeng, Cheng
    Ling, Yunhan
    Wang, Jianjun
    Xu, Guiying
    SURFACE & COATINGS TECHNOLOGY, 2016, 286 : 36 - 41
  • [5] Synthesis and properties of Fe-W powder
    Minic, DM
    Kák, T
    Schneeweiss, O
    Pizúrová, N
    Ristic, MM
    CZECHOSLOVAK JOURNAL OF PHYSICS, 2005, 55 (07) : 823 - 834
  • [6] Preparation and magnetic properties of Fe-W and Ni-W composite coatings
    Chiriac, H.
    Moga, A. E.
    Gherasim, C.
    Lupu, N.
    CAS 2007 INTERNATIONAL SEMICONDUCTOR CONFERENCE, VOLS 1 AND 2, PROCEEDINGS, 2007, : 307 - 310
  • [7] Effect of a multilayer structure and lubrication on the tribological properties of coatings of Fe-W alloys
    N. I. Tsyntsaru
    Zh. I. Bobanova
    D. M. Kroitoru
    V. F. Cheban
    G. I. Poshtaru
    A. I. Dikusar
    Surface Engineering and Applied Electrochemistry, 2010, 46 : 538 - 546
  • [8] Effect of a Multilayer Structure and Lubrication on the Tribological Properties of Coatings of Fe-W Alloys
    Tsyntsaru, N. I.
    Bobanova, Zh. I.
    Kroitoru, D. M.
    Cheban, V. F.
    Poshtaru, G. I.
    Dikusar, A. I.
    SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY, 2010, 46 (06) : 538 - 546
  • [9] Enhanced Tribological Properties of Electrodeposited Fe-W Alloy Coatings through Carburization
    Jamal, Ahsan
    Haq, Gulfam-Ul
    Hussain, Shabbir
    Gul, Maria
    Saifullah, Muhammad
    Anjum, Mohsin Ali Raza
    LANGMUIR, 2023, 39 (46) : 16328 - 16335
  • [10] AMORPHIZATION OF ELECTRODEPOSITED FE-W ALLOY-FILMS AND ELECTROCHEMICAL-BEHAVIOR
    RUAN, YF
    YAO, SW
    KOWAKA, M
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 117 : 752 - 755
12345