Novel chiral aminophosphine ligand: Synthesis and application in asymmetric catalytic hydrogenation reaction

被引：0
|
作者：
Chen, YX [1 ]
Li, YM
Lam, KH
Chan, ASC
机构：
[1] Guangzhou Univ, Dept Chem, Guangzhou 510405, Guangdong, Peoples R China
[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Inst Mol Technol, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2003年 / 21卷 / 01期
关键词：
aminophosphine; chiral ligand; 6,6 '-dimethoxy-2,2 '-bis(diphenylphosphinoamino)biphenyl; asymmetric hydrogenation;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new chiral aminophosphine ligand 6,6'-dimethoxy-2,2'-bis(diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodium complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic acid and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.
引用
收藏
页码：66 / 70
页数：5
相关论文
共 50 条
  • [1] Novel Chiral Aminophosphine Ligand: Synthesis and Application in Asymmetric Catalytic Hydrogenation Reaction
    陈亿新
    李月明
    林剑虹
    陈新滋
    ChineseJournalofChemistry, 2003, (01) : 66 - 70
  • [2] Asymmetric synthesis XXVIII: Novel chiral aminophosphine phosphinite ligand and its application in homogeneous catalytic asymmetric hydrogenation of dehydroamino acid derivatives
    Mi, AQ
    Lou, RG
    Jiang, YZ
    Deng, JG
    Qin, Y
    Fu, FM
    Hu, WH
    Chan, ASC
    SYNLETT, 1998, (08) : 847 - +
  • [3] Novel chiral 1,2-diphenyl-2-aminophosphine phosphinite ligands and their application in asymmetric catalytic hydrogenation
    Mi, AQ
    Lou, RL
    Jiang, YZ
    Hu, WH
    Fu, FM
    Li, Z
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U469 - U469
  • [4] Synthesis of new chiral diphosphine ligand (BisbenzodioxanPhos) and its application in asymmetric catalytic hydrogenation
    Pai, CC
    Li, YM
    Zhou, ZY
    Chan, ASC
    TETRAHEDRON LETTERS, 2002, 43 (15) : 2789 - 2792
  • [5] New chiral aminophosphine carboxyphosphinite ligands (AMPCP). Synthesis and application in asymmetric hydrogenation and hydroformylation
    Naili, S
    Mortreux, A
    Agbossou, F
    TETRAHEDRON-ASYMMETRY, 1998, 9 (19) : 3421 - 3430
  • [6] Synthesis of novel chiral benzophospholanes and their application in asymmetric hydrogenation
    Shimizu, H
    Saito, T
    Kumobayashi, H
    ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) : 185 - 189
  • [7] Chiral ruthenium aminophosphine (PN) and phosphine iminopyridine (PNN) complexes: Synthesis and application to asymmetric hydrogenation and transfer hydrogenation
    Scarlet, Littlelet
    Maragh, Paul
    Dasgupta, Tara
    Abdur-Rashid, Kamaluddin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [8] Synthesis of novel BINOL-derived chiral bisphosphorus ligands and their application in catalytic asymmetric hydrogenation
    Zhou, YG
    Zhang, XM
    CHEMICAL COMMUNICATIONS, 2002, (10) : 1124 - 1125
  • [9] Chiral aminophosphine complexes: Synthesis, characterization, and application to asymmetric catalysis
    Scarlet, Littlelet N.
    Maragh, Paul
    Dasgupta, Tara
    Abdur-Rashid, Kamaluddin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [10] Synthesis of optically active atropisomeric aminophosphine and its application to catalytic asymmetric reaction.
    Mino, T
    Tanaka, Y
    Sakamoto, M
    Fujita, T
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U552 - U552
12345