Selective hydrogenation of amides to alcohols in water solvent over a heterogeneous CeO2-supported Ru catalyst

被引：21
|
作者：
Tamura, Masazumi [1 ]
Ishikawa, Susumu [1 ]
Betchaku, Mii [1 ]
Nakagawa, Yoshinao [1 ]
Tomishige, Keiichi [1 ]
机构：
[1] Tohoku Univ, Grad Sch Engn, Aoba Ku, Aoba 6-6-07, Sendai, Miyagi 9808579, Japan
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 54期
关键词：
CHEMOSELECTIVE REDUCTION; EFFICIENT APPROACH; TERTIARY AMIDES; AMINES; SECONDARY; AMINOBOROHYDRIDES; POWERFUL; COMPLEX;
D O I：
10.1039/c8cc02697a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
CeO2-supported Ru (Ru/CeO2) worked as an effective and reusable heterogeneous catalyst for the selective dissociation of the C-N bond in amides, particularly primary amides, with H-2 in water solvent at low reaction temperature of 333 K, and high yields of the corresponding alcohols were obtained from primary amides.
引用
收藏
页码：7503 / 7506
页数：4
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