β-Oxochlorin cobalt(ii) complexes catalyze the electrochemical reduction of CO2

被引：6

作者：

Nganga, John ^{[1
]}

Chaudhri, Nivedita ^{[1
]}

Bruckner, Christian ^{[1
]}

Angeles-Boza, Alfredo M. ^{[1
,2
]}

机构：

[1] Univ Connecticut, Dept Chem, 55 N Eagleville Rd, Storrs, CT 06269 USA

[2] Univ Connecticut, Inst Mat Sci, 97 N Eagleville Rd, Storrs, CT 06269 USA

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 36期

基金：

美国国家科学基金会;

关键词：

CARBON-DIOXIDE; PHOTOCATALYTIC REDUCTION; PORPHYRINS; IRON; LIGAND; CONVERSION; EFFICIENT; METHANE; ISOBACTERIOCHLORIN; HYDROGENATION;

D O I：

10.1039/d1cc00573a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inspired by the architecture of the macrocycle of heme d(1), a series of synthetic mono-, di- and tri-beta-oxo-substituted porphyrinoid cobalt(ii) complexes were evaluated as electrocatalytic CO2 reducers, identifying complexes of unusually high efficiencies in generating multi-electron reduction products, including CH4.

引用

页码：4396 / 4399

页数：4

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