Pair of chiral 2D silver(i) enantiomers: chiral recognition of l- and d-histidine via differential pulse voltammetry

被引：10

作者：

Kim, Dongwon ^{[1
]}

Seo, Kyeong-Deok ^{[1
]}

Shim, Yoon-Bo ^{[1
]}

Lee, Kyungsuh ^{[1
]}

Lee, Sang Hak ^{[1
]}

Lee, Young-A ^{[2
]}

Jung, Ok-Sang ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Busan 46241, South Korea

[2] Jeonbuk Natl Univ, Dept Chem, Jeonju 54896, South Korea

来源：

DALTON TRANSACTIONS | 2022年 / 51卷 / 15期

基金：

新加坡国家研究基金会;

关键词：

ELECTROANALYSIS; DISCRIMINATION; POLLUTANTS; LIGAND;

D O I：

10.1039/d1dt03371a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of AgPF6 with a pair of chiral tridentate ligands (1S,1 ' S,1 '' S,2R,2 ' R,2 '' R) and (1R,1 ' R,1 '' R,2S,2 ' S,2 '' S)-(benzenetricarbonyltris(azanediyl))tris(2,3-dihydro-1H-indene-2,1-diyl)triisonicotinate (s,r-L) and (r,s-L) in a mixture of methanol and dioxane yields 2D sheets consisting of [Ag(s,r-L)](PF6)center dot 3C(4)H(8)O(2)center dot 0.5H(2)O and [Ag(r,s-L)](PF6)center dot 3C(4)H(8)O(2)center dot 0.5H(2)O, respectively. The differential pulse voltammetric (DPV) technique using the pair of chiral 2D-sheet enantiomers was employed for chiral discrimination of amino acid enantiomers, and was found to be an effective tool for enantio-recognition of l- and d-histidines. Both the size and the binding site of amino acids were strongly dependent on electrochemical enantio-recognition via the chiral 2D sheets.

引用

页码：6046 / 6052

页数：7

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