Flow-vacuum pyrolysis of polycyclic compounds. 12 Pyrolysis of 10,11-dihydro-5-methylene-5H-dibenzo[a,d]cyclohepten and of 10,11-dihydro-5-methyl-5H-dibenzo[a,d]cycloheptene

被引：0
|
作者：
Banciu, MD
Mangra, C
Petride, A
机构：
[1] Polytech Univ Bucharest, Organ Chem Lab, R-76206 Bucharest, Romania
[2] Roumanian Acad, CD Nenitzescu Inst Organ Chem, R-78100 Bucharest, Romania
来源：
REVUE ROUMAINE DE CHIMIE | 1997年 / 42卷 / 07期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Flow-vacuum pyrolyses of the title hydrocarbons afford anthracene and 9-methylanthracene as main products. The reaction mechanism suggested by Trahanovsky(2) for pyrolysis of dibenzocyctooctene- and dibenzocycloheptene derivatives is confirmed. For secondary products, parallel radicalic routes are suggested.
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页码：565 / 569
页数：5
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