Crossed beam studies of radical-radical reactions:: O(3P)+C3H5 (allyl)

被引：32
|
作者：
Leonori, F.
Balucani, N.
Capozza, G.
Segoloni, E.
Stranges, D.
Casavecchia, P.
机构：
[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
[2] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2007年 / 9卷 / 11期
关键词：
MOLECULAR-BEAM; ANGULAR-DISTRIBUTIONS; PERSISTENT COMPLEXES; REACTION DYNAMICS; SCATTERING; ATOMS; OXYGEN;
D O I：
10.1039/b618971g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The dynamics of the radical-radical reaction O(P-3) + C3H5 has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol(-1); the reaction mechanism of the H- displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C-C bond-breaking channels at this collision energy has been obtained.
引用
收藏
页码：1307 / 1311
页数：5
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