Role of Noncovalent Interactions in Vanadium Tellurite Chain Con nectivities

被引：14

作者：

Nourmahnad, Anahita ^{[1
]}

Smith, Matthew D. ^{[1
]}

Zeller, Matthias ^{[2
]}

Ferrence, Gregory M. ^{[3
]}

Schrier, Joshua ^{[1
]}

Norquist, Alexander J. ^{[1
]}

机构：

[1] Haverford Coll, Dept Chem, Haverford, PA 19041 USA

[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

[3] Illinois State Univ, Dept Chem, Normal, IL 61790 USA

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 02期

基金：

美国国家科学基金会;

关键词：

CENTER-DOT-O; COMPOSITION SPACE ANALYSIS; MELTING-POINT ALTERNATION; BOND-VALENCE PARAMETERS; NONCENTROSYMMETRIC MOLYBDATES; HYDROGEN-BOND; STRUCTURAL DIVERSITY; INTERACTION REGIONS; DIRECTED SYNTHESIS; ORGANIC FRAMEWORK;

D O I：

10.1021/ic502753e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structural differences in [V2Te2O10](n)(2n-) chain metrics are directly ascribed to variations in noncovalent interactions in a series of organically templated vanadium tellurites, including [C6H17N3][V2Te2O10].H2O, [C5H16N2][V2Te2O10], and [C4H14N2][V2Te2O10]. The noncovalent interaction (NCI) method was used to locate, quantify, and visualize intermolecular interactions in [C4H14N2][V2Te2O10] and [C5H16N2][V2Te2O10]. Variations in the van der Waals attractions between [1,4-diaminobutaneH2](2+) and [1,5-diaminopentaneH(2)](2+) result in divergent packing motifs for these cations, which causes a reorganization of N-H...O hydrogen bonding and variances in the [V2Te2O10](n)(2n-) chain metrics. The application of the NCI method to this type of solid-state structure provides a direct method to elucidate the structural effects of weak noncovalent interactions.

引用

页码：694 / 703

页数：10

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