A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation

被引：216

作者：

Widegren, Magnus B. ^{[1
]}

Harkness, Gavin J. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Cordes, David B. ^{[1
]}

Clarke, Matthew L. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 21期

基金：

英国工程与自然科学研究理事会;

关键词：

enantioselective catalysis; ester hydrogenation; ferrocene; manganese; reduction; ASYMMETRIC ALKENE HYDROGENATION; CHIRAL TRIDENTATE LIGAND; CARBOXYLIC-ACID ESTERS; C-H ACTIVATION; PINCER COMPLEXES; SELECTIVE HYDROGENATION; IRIDIUM CATALYSTS; RUTHENIUM COMPLEX; AROMATIC KETONES; COBALT CATALYST;

D O I：

10.1002/anie.201702406

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anew hydrogenation catalyst based onamanganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol% catalyst loading, and gives up to 97% ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 degrees C.

引用

页码：5825 / 5828

页数：4

共 50 条

[1] A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation (vol 56, pg 5825, 2017)
Widegren, M. B.
Harkness, G. J.
Slawin, A. M. Z.
Cordes, D. B.
Clarke, M. L.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (32) : 9265 - 9265
[2] A highly reusable catalyst for enantioselective ketone hydrogenation. Catalyst-organic frameworks by alternating ROMP assembly
Ralph, Corbin K.
Bergens, Steven H.
ORGANOMETALLICS, 2007, 26 (07) : 1571 - 1574
[3] BENZOPHENONE-DERIVED CATALYST WITH SELF-ADAPTATION: HIGHLY ENANTIOSELECTIVE HYDROGENATION IRRESPECTIVE OF KETONE SUBSTRATES
Wakabayashi, Kazuki
Aikawa, Kohsuke
Mikami, Koichi
HETEROCYCLES, 2008, 76 (02) : 1525 - 1535
[4] Enantioselective Ketone Hydroacylation Using Noyori's Transfer Hydrogenation Catalyst
Murphy, Stephen K.
Dong, Vy M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (15) : 5553 - 5556
[5] Achiral benzophenone ligand for highly enantioselective Ru catalysts in ketone hydrogenation
Mikami, K
Wakabayashi, K
Aikawa, K
ORGANIC LETTERS, 2006, 8 (08) : 1517 - 1519
[6] HIGHLY-ACTIVE CATALYSTS FOR ENANTIOSELECTIVE HYDROGENATION OF KETONES
TANI, K
SUWA, K
OTSUKA, S
ACS SYMPOSIUM SERIES, 1982, 185 : 283 - 284
[7] A NEW AND HIGHLY ACTIVE CATALYST FOR HOMOGENEOUS HYDROGENATION
JARDINE, I
MCQUILLI.FJ
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (09): : 477 - &
[8] HIGHLY ACTIVE MOLYBDENUM CATALYST FOR ALKENE HYDROGENATION
BRENNER, A
JOURNAL OF MOLECULAR CATALYSIS, 1979, 5 (02): : 157 - 161
[9] A versatile cobalt catalyst for highly enantioselective hydrogenation of carbonyl compounds
Du, Xiaoyong
Zhang, Yao
Yang, Tilong
Xiao, Ye
He, Jian
Chung, Lung Wa
Chen, Gen-Qiang
Zhang, Xumu
CHEM CATALYSIS, 2024, 4 (05):
[10] Highly Enantioselective Hydrogenation of β-Ketoenamides with the Rh-ZhangPhos Catalyst
Huang, Kexuan
Zhang, Xiaowei
Geng, Huiling
Li, Sheng-kun
Zhang, Xumu
ACS CATALYSIS, 2012, 2 (07): : 1343 - 1345

← 1 2 3 4 5 →