The reaction of triptycene haloquinones with alkoxides. An unusual route to pentiptycene quinones

被引：12
|
作者：
Spyroudis, S [1 ]
Xanthopoulou, N [1 ]
机构：
[1] Univ Thessaloniki, Dept Chem, Organ Chem Lab, Thessaloniki 54124, Greece
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 19期
关键词：
triptycene quinones; pentiptycene quinones; haloquinones;
D O I：
10.1016/S0040-4039(03)00755-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triptycene haloquinones 3 react with sodium alkoxides in refluxing alcohol to afford, besides the expected substitution products, pentiptycene quinone 4. This approach to 4 is compared with a Diels-Alder strategy to the same compound. (C) 2003 Elsevier Science Ltd. All rights reserved.
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页码：3767 / 3770
页数：4
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