The formation kinetics of Sr2FeMoO6 (SFMO) was diagnosed during the solid-state reaction of SrFeO3-x and SrMoO4 at different temperatures and heating rates. The reaction kinetics was analyzed by X-ray diffractometer, and the extent of the reaction was quantified by the internal standard method. The non-isothermal kinetic empirical model was proposed to evaluate the activation energy and rate constant of SFMO and further justified to be valid to picture the reaction kinetics of SFMO. (C) 2005 Springer Science + Business Media, Inc.
机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
Causa, MT
Butera, A
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机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
Butera, A
Tovar, M
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Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, ArgentinaComis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
Tovar, M
Folatcuberta, J
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机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
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Univ Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
GILDA ESRF, CNR TASC Lab, Grenoble, FranceUniv Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
Meneghini, C.
Ray, Sugata
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Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
Indian Assoc Cultivat Sci, Dept Mat Sci, Kolkata, India
Indian Assoc Cultivat Sci, Ctr Adv Mat, Kolkata, IndiaUniv Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
Ray, Sugata
Liscio, F.
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Univ Roma Tre, Dipartimento Fis, I-00146 Rome, ItalyUniv Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
Liscio, F.
Bardelli, F.
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Univ Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
GILDA ESRF, CNR TASC Lab, Grenoble, FranceUniv Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
Bardelli, F.
Mobilio, S.
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Univ Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
GILDA ESRF, CNR TASC Lab, Grenoble, France
Ist Nazl Fis Nucl, Lab Nazl Frascati, I-00044 Frascati, ItalyUniv Roma Tre, Dipartimento Fis, I-00146 Rome, Italy
Mobilio, S.
Sarma, D. D.
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Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
Indian Assoc Cultivat Sci, Ctr Adv Mat, Kolkata, IndiaUniv Roma Tre, Dipartimento Fis, I-00146 Rome, Italy