Sustainable Electrical Energy Storage through the Ferrocene/Ferrocenium Redox Reaction in Aprotic Electrolyte

被引：140

作者：

Zhao, Yu ^{[1
,2
]}

Ding, Yu ^{[1
,2
]}

Song, Jie ^{[1
,2
]}

Li, Gang ^{[3
]}

Dong, Guangbin ^{[3
]}

Goodenough, John B. ^{[1
,2
]}

Yu, Guihua ^{[1
,2
]}

机构：

[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA

[2] Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA

[3] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 41期

关键词：

energy storage; ferrocene; Li-redox batteries; metallocenes; sustainable chemistry; RECHARGEABLE LITHIUM BATTERIES; SECONDARY BATTERIES; AQUEOUS CATHODE; FLOW BATTERIES; FERROCENE; PHASE; THERMODYNAMICS; DERIVATIVES; CHALLENGES; DIFFUSION;

D O I：

10.1002/anie.201406135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The large-scale, cost-effective storage of electrical energy obtained from the growing deployment of wind and solar power is critically needed for the integration into the grid of these renewable energy sources. Rechargeable batteries having a redox-flow cathode represent a viable solution for either a Li-ion or a Na-ion battery provided a suitable low-cost redox molecule soluble in an aprotic electrolyte can be identified that is stable for repeated cycling and does not cross the separator membrane to the anode. Here we demonstrate an environmentally friendly, low-cost ferrocene/ferrocenium molecular redox couple that shows about 95% energy efficiency and about 90% capacity retention after 250 full charge/discharge cycles.

引用

页码：11036 / 11040

页数：5

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