Synthesis of fluorinated block copolymers and their application as novel polymerisation surfactants in supercritical carbon dioxide

被引：42
|
作者：
Yong, TM
Hems, WP
vanNunen, JLM
Holmes, AB
Steinke, JHG
Taylor, PL
Segal, JA
Griffin, DA
机构：
[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV CAMBRIDGE,DEPT CHEM,MELVILLE LAB POLYMER SYNTH,CAMBRIDGE CB2 3RA,ENGLAND
[3] ICI PAINTS,DECORAT RES,SLOUGH SL2 5DS,BERKS,ENGLAND
[4] ICI ACRYL,MIDDLESBROUGH TS90 8JE,CLEVELAND,ENGLAND
[5] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 18期
关键词：
D O I：
10.1039/a705399a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Screened anionic copolymerisation of methyl methacrylate with the perfluoroalkyl methacrylates 2 affords well-defined AB block copolymers 4-6, which serve as effective surfactants in the dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide.
引用
收藏
页码：1811 / 1812
页数：2
相关论文
共 50 条
  • [1] Dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide - evaluation of well defined fluorinated AB block copolymers as surfactants
    Hems, WP
    Yong, TM
    van Nunen, JLM
    Cooper, AI
    Holmes, AB
    Griffin, DA
    JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (07) : 1403 - 1407
  • [2] Macromolecular surfactants for supercritical carbon dioxide applications: Synthesis and characterization of fluorinated block copolymers prepared by nitroxide mediated radical polymerization
    Lacroix-Desmazes, P
    Andre, P
    Desimone, JM
    Ruzette, AV
    Boutevin, B
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (14) : 3537 - 3552
  • [3] Phase behavior of novel fluorinated surfactants in supercritical carbon dioxide
    Liu, Zhao-Tie
    Wu, Jin
    Liu, Ling
    Song, Liping
    Gao, Ziwei
    Dong, Wensheng
    Lu, Jian
    GREEN CHEMISTRY, 2006, 8 (11) : 978 - 983
  • [4] Microemulsions formed with novel fluorinated surfactants in supercritical carbon dioxide
    Liu, Zhao-Tie
    Wu, Jin
    Liu, Ling
    Gao, Ziwei
    Lu, Jian
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [5] Surface hydrophobicity of fluorinated block copolymers enhanced by supercritical carbon dioxide annealing
    Yokoyama, H
    Sugiyama, K
    LANGMUIR, 2004, 20 (23) : 10001 - 10006
  • [6] Synthesis of fluorinated block copolymers by nitroxide-mediated radical polymerization for supercritical carbon dioxide applications.
    Lacroix-Desmazes, P
    Boutevin, B
    Taylor, DK
    DeSimone, JM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U445 - U446
  • [7] New unsaturated surfactants for the dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide
    Giles, MR
    Howdle, SM
    EUROPEAN POLYMER JOURNAL, 2001, 37 (07) : 1347 - 1351
  • [8] Synthesis of fluorinated oligomers for supercritical carbon dioxide applications
    Bilgin, N
    Baysal, C
    Menceloglu, YZ
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (21) : 5312 - 5322
  • [9] Synthesis of poly(p-dioxanone)-based block copolymers in supercritical carbon dioxide
    Tianqiang Wang
    Yu Liu
    Jianyuan Hao
    Colloid and Polymer Science, 2014, 292 : 2497 - 2508
  • [10] Synthesis of poly(p-dioxanone)-based block copolymers in supercritical carbon dioxide
    Wang, Tianqiang
    Liu, Yu
    Hao, Jianyuan
    COLLOID AND POLYMER SCIENCE, 2014, 292 (10) : 2497 - 2508
12345