Synthesis and structural characterization of azatitanacyclobutane derivatives

被引：0
|
作者：
Beckhaus, R [1 ]
Wagner, M [1 ]
Wang, RM [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 1998年 / 02期
关键词：
titanium; vinylidene complexes; 2+2] cycloaddition; metallacycles; azatitanacyclobutanes; clathrates;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The titanocene vinylidene intermediate [Cp-2*Ti=C=CH2] (9) reacted with the carbodiimides R-N=C=N-R [R = p-CH3C6H4 (19a), C6H11 (19b)] to give the N=C-cycloaddition products [(Cp2Ti)-Ti-*{-NR-C(=NR)-(C=CH2)-}] [(R = p-CH3C6H4 (20a), C6H11 (20b)]. The X-ray structure of 20a in form of a surprisingly stable n-hexane clathrate is presented. The azatitanacyclobutane [(Cp2Ti)-Ti-*{-NPh-C(Ph)(H)-(C=CH2)-}] (22) was formed from the reaction between 9 and benzylidene aniline [PhN=C(Ph)H (21)]. Reactivity studies showed that azatitanacyclobutanes are unreactive upon typical ring-enlargement reactions as observed for other four-membered titanacycles.
引用
收藏
页码：253 / 256
页数：4
相关论文
共 50 条
  • [1] Synthesis and structural characterization of novel β-tropolone derivatives
    Komissarov, VN
    Bang, DN
    Minkin, VI
    Aldoshin, SM
    Tkachev, VV
    Shilov, GV
    MENDELEEV COMMUNICATIONS, 2003, (05) : 219 - 221
  • [2] Synthesis and structural characterization of ferrocenyl indenyl derivatives
    Luo, Mei-Hua
    Han, Li-Min
    Zhu, Ning
    Hong, Hai-Long
    Xie, Rui-Jun
    Suo, Quan-Ling
    Weng, Lin-Hong
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (21) : 3805 - 3815
  • [3] Synthesis, Spectral, and Structural Characterization of Bisthiocarbohydrazone Derivatives
    Kumar, S. L. Ashok
    Kumar, M. Saravana
    Jenniefer, S. Jegan
    Muthiah, P. Thomas
    Sreekanth, A.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2013, 188 (08) : 1110 - 1118
  • [4] Synthesis and structural characterization of new benzimidazole derivatives
    Destefano, Matthew R.
    Nellist, Michael R.
    Geiger, David K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [5] Synthesis and Structural Characterization of p-Carboranylamidine Derivatives
    Harmgarth, Nicole
    Liebing, Phil
    Lorenz, Volker
    Engelhardt, Felix
    Hilfert, Liane
    Busse, Sabine
    Goldhahn, Ruediger
    Edelmann, Frank T.
    MOLECULES, 2023, 28 (09):
  • [6] Synthesis, structural characterization, and cytotoxic evaluation of chalcone derivatives
    Paulo N. Bandeira
    Telma L. G. Lemos
    Hélcio S. Santos
    Mylena C. S. de Carvalho
    Daniel P. Pinheiro
    Manoel O. de Moraes Filho
    Cláudia Pessoa
    Francisco W. A. Barros-Nepomuceno
    Tigressa H. S. Rodrigues
    Paulo R. V. Ribeiro
    Herbert S. Magalhães
    Alexandre M. R. Teixeira
    Medicinal Chemistry Research, 2019, 28 : 2037 - 2049
  • [7] New methyl dehydroabietate derivatives:: Synthesis and structural characterization
    Silvestre, AJD
    Monteiro, SMC
    Silva, AMS
    Cavaleiro, JAS
    Félix, VMS
    Ferreira, P
    Drew, MGB
    MONATSHEFTE FUR CHEMIE, 1998, 129 (11): : 1183 - 1197
  • [8] Synthesis and structural characterization of novel tetranuclear organotitanoxane derivatives
    Ventura, Maria
    Ramirez de Arellano, Carmen
    Mosquera, Marta E. G.
    Jimenez, Gerardo
    Cuenca, Tomas
    DALTON TRANSACTIONS, 2011, 40 (21) : 5728 - 5733
  • [9] Synthesis, structural characterization and anticancer evaluation of pyrazole derivatives
    Mohamed S. A. El-Gaby
    Mustafa M. Ghorab
    Zainb H. Ismail
    Soad. M. Abdel-Gawad
    Hala. M. Aly
    Medicinal Chemistry Research, 2018, 27 : 72 - 79
  • [10] Synthesis, structural characterization, and cytotoxic evaluation of chalcone derivatives
    Bandeira, Paulo N.
    Lemos, Telma L. G.
    Santos, Helcio S.
    de Carvalho, Mylena C. S.
    Pinheiro, Daniel P.
    de Moraes Filho, Manoel O.
    Pessoa, Claudia
    Barros-Nepomuceno, Francisco W. A.
    Rodrigues, Tigressa H. S.
    Ribeiro, Paulo R., V
    Magalhaes, Herbert S.
    Teixeira, Alexandre M. R.
    MEDICINAL CHEMISTRY RESEARCH, 2019, 28 (11) : 2037 - 2049
12345