Photochemical reactions of 9-trimethylstannylanthracene in various solvents

被引：1

作者：

Ivanov, V. L. ^{[1
]}

Roznyatovskii, V. A.

Zemlyanskii, N. N.

Borisova, I. V.

Ustynyuk, Yu. A.

Buchachenko, A. L.

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

[2] Moscow MV Lomonosov State Univ, Ctr Magnet Tomog & Spect, Moscow 119992, Russia

[3] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0036024406040261

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

9-Trimethylstannylanthracene (1) was synthesized and its photolysis by 365-nm light was studied. In aprotic solvents, the dimerization of 1 involves positions 9 and 10 and yields a head-to-tail dimer. The main route of the photolysis of 1 in alcohols is the cleavage of the C-Sn bond with the formation of anthracene. The quantum yields of the photoreaction and the lifetimes and quantum yields of 1 fluorescence were determined.

引用

页码：626 / 629

页数：4

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