Flexible cycloalkyl-substituted N-heterocyclic carbenes

被引：18
|
作者：
Fortman, George C. [1 ]
Slawin, Alexandra M. Z. [1 ]
Nolan, Steven P. [1 ]
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 16期
关键词：
RESTRICTED FLEXIBILITY; COMPLEXES; LIGANDS; CATALYSIS; IRIDIUM; METAL; RHODIUM; SYSTEM;
D O I：
10.1039/c003214j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The use of two metal systems cis-Pt(NHC)(2)Me(2) and cis-Ir(NHC)(CO)(2)Cl help to highlight the. exibility of a series of cycloalkyl-substituted N-heterocyclic carbene ligands (ICy, ICy(7), ICy(8), ICy(12)). Bond dissociation enthalpies of several N-heterocyclic carbenes (NHCs) in cis-Pt(NHC)(2)Me(2) are estimated. Electronic and steric parameters of the ICy(n) ligands are quantified and discussed.
引用
收藏
页码：3923 / 3930
页数：8
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