CAN-mediated oxidative free radical reactions in an ionic liquid

被引：34
|
作者：
Bar, G [1 ]
Bini, F [1 ]
Parsons, AF [1 ]
机构：
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
来源：
SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 02期
关键词：
radical reactions; ionic liquids;
D O I：
10.1081/SCC-120015703
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.
引用
收藏
页码：213 / 222
页数：10
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