Manganese-Catalyzed Allylation of Quinazolinones with 4-Vinyl-1,3-dioxolan-2-one via C-H Activation

被引：2
|
作者：
Li Yudong [1 ,2 ]
Li Ying [1 ]
Dong Ya'nan [1 ]
Xia Chungu [1 ]
Li Yuehui [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 42卷 / 03期
基金：
中国国家自然科学基金;
关键词：
manganese-catalyzed; allylation; quinazolinones; C-H activation; EXPEDIENT ACCESS; BOND FORMATION; FUNCTIONALIZATION; ARYLATION; SULFAMIDATION; STRATEGIES; ALDEHYDES; IMINES;
D O I：
10.6023/cjoc202110002
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The ortho-allylation of quinazolinones with 4-vinyl-1,3-dioxolan-2-one via manganese catalysis has been described. A series of allylation products with potential applications have been obtained. This protocol is also highlighted by good compatibility of functional groups and excellent E/Z selectivity. This work broadens the scope of Mn-catalyzed C-C coupling reactions.
引用
收藏
页码：847 / 853
页数：7
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