(E)-1-[(2-Fluorophenyl)iminomethyl]-2-naphthol-(Z)-1-[(2-fluorophenyl)aminomethylidene]naphthalen-2(1H)-one (0.57/0.43)

被引:2
|
作者
Alpaslan, Goekhan [1 ]
Macit, Mustafa [2 ]
Bueyuekguengoer, Orhan [1 ]
Erdoenmez, Ahmet [1 ]
机构
[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Kurupelit, Turkey
[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Turkey
关键词
SCHIFF-BASES; TAUTOMERISM;
D O I
10.1107/S1600536810014777
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title Schiff base compound, 0.57C(17)H(12)FNO center dot 0.43C(17)H(12)-FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57 (6) and 0.43 (6), respectively. The tautomeric forms are stabilized by intramolecular O-H center dot center dot center dot N (enol) and N-H center dot center dot center dot O (keto) hydrogen bonds. The dihedral angle between the naphthalene ring system and the benzene ring is 32.76 (1)degrees.
引用
收藏
页码:O1178 / U984
页数:9
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