Selenocyanation of Aryl and Styryl Methyl Ketones in the Presence of Selenium Dioxide and Malononitrile: An Approach for the Synthesis of α-Carbonyl Selenocyanates

被引：15

作者：

Marpna, Ibakyntiew D. ^{[1
]}

Wanniang, Kmendashisha ^{[1
]}

Lipon, Tyrchain Mitre ^{[1
]}

Shangpliang, O. Risuklang ^{[1
]}

Myrboh, Bekington ^{[1
]}

机构：

[1] North Eastern Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 86卷 / 02期

关键词：

ONE-POT SYNTHESIS; ORGANOSELENIUM COMPOUND; AROMATIC KETONES; 1,4-PHENYLENEBIS(METHYLENE)SELENOCYANATE; PROTOCOL; SE;

D O I：

10.1021/acs.joc.0c02630

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient method has been developed for the synthesis of alpha-carbonyl selenocyanates from aryl methyl ketones/styryl methyl ketones using selenium dioxide as the selenating agent under simple reaction conditions. This reaction has notable advantages over the traditional methods in terms of accessibility and affordability of the starting materials. The method features the interaction of aryl methyl ketones/styryl methyl ketones with selenium dioxide and malononitrile to afford a series of alpha-carbonyl selenocyanates in moderate to good yields.

引用

页码：1980 / 1986

页数：7

共 15 条

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TETRAHEDRON LETTERS, 2004, 45 (23) : 4461 - 4463
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Shangpliang, O. Risuklang
Kshiar, Baskhemlang
Wanniang, Kmendashisha
Marpna, Ibakyntiew D.
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Laloo, Badaker M.
Myrboh, Bekington
JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (10): : 5829 - 5835
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Young, Ryan M.
Davies-Coleman, Michael T.
TETRAHEDRON LETTERS, 2011, 52 (31) : 4036 - 4038
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Ali, Danish
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Panday, Anoop Kumar
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ACS OMEGA, 2023, 8 (28): : 25349 - 25357
[5] PTSA-Catalyzed Reaction of Alkyl/Aryl Methyl Ketones with Aliphatic Alcohols in the Presence of Selenium Dioxide: A Protocol for the Generation of an α-Ketoacetals Library
Shangpliang, O. Risuklang
Wanniang, Kmendashisha
Kshiar, Baskhemlang
Marpna, Ibakyntiew D.
Lipon, Tyrchain Mitre
Mizar, Pushpak
Myrboh, Bekington
ACS OMEGA, 2019, 4 (03): : 6035 - 6043
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Laloo, Badaker M.
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Kharkongor, Icydora
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JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (01): : 707 - 712
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RYANG, M
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Myrboh, Bekington
TETRAHEDRON LETTERS, 2015, 56 (29) : 4359 - 4362
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Devaraju, Mohankumar
Dasappa, Jagadeesh Prasad
ORGANIC & BIOMOLECULAR CHEMISTRY, 2025, 23 (12) : 2891 - 2895

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