Synthesis and crystal structure of Rb6Pb5Cl16

被引：0

作者：

Beck, HP ^{[1
]}

Schramm, M

Haberkorn, R

Dinnebier, R

Stephens, PW

机构：

[1] Univ Saarlandes, Fachrichtung Anorgan & Analyt Chem & Radiochem, D-66123 Saarbrucken, Germany

[2] Univ Bayreuth, Inst Crystallog, Bayreuth, Germany

[3] Brookhaven Natl Lab, Natl Synchrotron Light Source, Upton, NY 11973 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 03期

关键词：

ternary halide; lone pair cation; high coordination;

D O I：

10.1002/(SICI)1521-3749(199803)624:3<393::AID-ZAAC393>3.0.CO;2-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a hitherto unknown 6:5 phase in the quasi-binary system RbCl/PbCl2 and its structure determination is reported. The compound Rb6Pb5Cl16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature of the structure is a statistical distribution of Rb and Pb at one of the cation sites with a ratio of 1:3 as defined by electroneutrality. There is no evidence for symmetry reduction by ordering.

引用

页码：393 / 398

页数：6

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