Solubility and mixing thermodynamics properties of erythromycin ethylsuccinate in different organic solvents

被引：15

作者：

Zhang, Xia ^{[1
]}

Yin, Qiuxiang ^{[1
,2
]}

Li, Xiang ^{[1
]}

Zhang, Meijing ^{[1
,2
]}

Huang, Jiting ^{[1
]}

Wang, Chang ^{[1
]}

Zhang, Zaixiang ^{[1
]}

Huang, Yaohui ^{[1
]}

Guo, Mingxia ^{[1
]}

Li, Yang ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, State Key Lab Chem Engn, Tianjin, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Chem Engn Tianj, Tianjin 300072, Peoples R China

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2017年 / 237卷

关键词：

Erythromycin ethylsuccinate; Solubility; Hansen solubility parameters; Mixing thermodynamic properties; DIFFERENT PURE SOLVENTS; VAPOR-LIQUID; SOLID DISPERSIONS; MELT EXTRUSION; NRTL EQUATION; PLUS WATER; PARAMETERS; MIXTURES; ACID; EQUILIBRIUM;

D O I：

10.1016/j.molliq.2017.04.081

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solid-liquid equilibrium data of erythromycin ethylsuccinate in six pure organic solvents including tetrahydrofuran, acetone, acetonitrile, hexane, ethanol and 2-propanol were determined by using the gravimetric method over the temperature range from 288.15 K to 323.15 K. The experimental solubility data was correlated by modified Apelblat equation, van't Hoff, Wilson, and NRTL model, among which the modified Apelblat model was found to have the best agreement with the experimental results. The mixing Gibbs free energy, mixing enthalpy, and mixing entropy were calculated by Non-random two liquid (NRTL) model. The solubility behavior of EES at given temperature were illustrated by Hansen SPs values. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：46 / 53

页数：8

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