Novel ruthenium(II) and zinc(II) complexes for two-photon absorption related applications

被引：51
|
作者：
Girardot, C.
Lemercier, G.
Mulatier, J.-C.
Chauvin, J.
Baldeck, P. L.
Andraud, C.
机构：
[1] Ecole Normale Super Lyon, CNRS, UMR 5182, Chim Lab, F-69364 Lyon 07, France
[2] Univ Grenoble 1, CNRS, ICMG FR 2607, UMR 5250,Dept Chim Mol, F-38041 Grenoble 9, France
[3] Univ Grenoble 1, CNRS, UMR 5588, Lab Spectrometrie Phys, F-38402 St Martin Dheres, France
[4] CNRS, F-38402 Lyon, France
来源：
DALTON TRANSACTIONS | 2007年 / 31卷 / 31期
关键词：
D O I：
10.1039/b706715a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new fluorene derivatized 1,10-phenanthroline ligands and related tris-chelate Ru(II) or Zn(II) coordination complexes have been synthesised. The linear and nonlinear (two-photon induced fluorescence) photophysical measurements have contributed to highlight the possibility to tune the absorption spectral range and excited lifetime, depending on ligand substitution and nature of the metal. More significantly, the observation of two-photon absorption (TPA) associated with long-lived metal-to-ligand charge-transfer (MLCT) excited states in the Ru(II)-based chromophores, opens a wide range of applications in the near infrared.
引用
收藏
页码：3421 / 3426
页数：6
相关论文
共 50 条
  • [1] Ruthenium(II) complexes for two-photon absorption-based optical power limiting
    Girardot, Camille
    Cao, Bertrand
    Mulatier, Jean-Christophe
    Baldeck, Patrice L.
    Chauvin, Jerome
    Riehl, Didier
    Delaire, Jacques A.
    Andraud, Chantal
    Lemercier, Gilles
    CHEMPHYSCHEM, 2008, 9 (11) : 1531 - 1535
  • [2] Uniting Ruthenium(II) and Platinum(II) Polypyridine Centers in Heteropolymetallic Complexes Giving Strong Two-Photon Absorption
    Shi, Pengfei
    Coe, Benjamin J.
    Sanchez, Sergio
    Wang, Daqi
    Tian, Yupeng
    Nyk, Marcin
    Samoc, Marek
    INORGANIC CHEMISTRY, 2015, 54 (23) : 11450 - 11456
  • [3] Sensitive ctDNA detection by a novel zinc(II) complex with two-photon absorption based on electrochemiluminescence
    Yang, Junsong
    Liu, Bing
    Wu, Jieying
    Zhang, Shengyi
    Jin, Baokang
    Tian, Yupeng
    NEW JOURNAL OF CHEMISTRY, 2015, 39 (02) : 1404 - 1409
  • [4] New Zinc(II) Dyes: Photophysical Properties and Enhanced Two-Photon Absorption
    Cao, Yuanle
    Xu, Dongling
    Yang, Mingdi
    Wang, Yang
    Zhou, Feixia
    Zhou, Hongping
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (12) : 6900 - 6906
  • [5] Ruthenium (II) polypyridyl complexes as two-photon absorbers and sensitizers: Design, structure-properties relationships and applications
    Fillaut, Jean-Luc
    COORDINATION CHEMISTRY REVIEWS, 2024, 518
  • [6] Two novel six-coordinated cadmium(II) and zinc(II) complexes from carbazate β-diketonate: crystal structures, enhanced two-photon absorption and biological imaging application
    Nie, Cuiyun
    Zhang, Qiong
    Ding, Hongjuan
    Huang, Bei
    Wang, Xinyan
    Zhao, Xianghua
    Li, Shengli
    Zhou, Hongping
    Wu, Jieying
    Tian, Yupeng
    DALTON TRANSACTIONS, 2014, 43 (02) : 599 - 608
  • [7] Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes
    Zhou, Hong-ping
    Li, Dong-mei
    Wang, Peng
    Cheng, Le-hua
    Gao, Yuan-hao
    Zhu, Yong-min
    Wu, Jie-ying
    Tian, Yu-peng
    Tao, Xu-tang
    Jiang, Min-hua
    Fun, Hoong-kun
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 826 (2-3) : 205 - 210
  • [8] Two-photon absorption of Zn(II) octupolar molecules
    Mazzucato, Simone
    Fortunati, Ilaria
    Scolaro, Sara
    Zerbetto, Michele
    Ferrante, Camilla
    Signorini, Raffaella
    Pedron, Danilo
    Bozio, Renato
    Locatelli, Danika
    Righetto, Stefania
    Roberto, Dominique
    Ugo, Renato
    Abbotto, Alessandro
    Archetti, Graziano
    Beverina, Luca
    Ghezzi, Sergio
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (23) : 2999 - 3005
  • [9] An investigation on the two-photon absorption activity of various terpyridines and related homoleptic andheteroleptic cationic Zn(II) complexes
    Righetto, S
    Rondena, S
    Locatelli, D
    Roberto, D
    Tessore, F
    Ugo, R
    Quici, S
    Roma, S
    Korystov, D
    Srdanov, VI
    JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (15) : 1439 - 1444
  • [10] One- and two-photon excited fluorescence of zinc(II), cadmium(II) complexes containing phenothiazine ligand
    Xue, ZM
    Tian, YP
    Wang, D
    Jiang, MH
    CHINESE CHEMICAL LETTERS, 2003, 14 (05) : 525 - 528
12345