The reactivities of perfluoroisopropyl and tert-butyl radicals towards hydrogen atom abstraction from triethylsilane

被引：0

作者：

Dolbier, WR ^{[1
]}

Li, AR ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 01期

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D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rates of hydrogen abstraction from triethylsilane by the highly electrophilic perfluoroisopropyl and perfluoro-tert-butyl radicals have been obtained through competition experiments, These rates, 3.6 x 10(6) and 2.4 x 10(8) M(-1) s(-1), respectively, are indicative of substantial reactivity enhancements, relative to perfluoro-n-alkyl radicals, derived from their enhanced electrophilicity and, in the latter case, from a much stronger forming C-H bond.

引用

页码：79 / 82

页数：4

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