Synthesis of helical shaped 1,1′-bibenzo[c]phenanthrene-2,2′-diol (HEBPOL) derivatives by reduction of helical quinones

被引：8

作者：

Shahabuddin, Mohammad ^{[1
]}

Ohgoshi, Keita ^{[1
]}

Hossain, Sharif ^{[1
]}

Kimura, Takao ^{[1
]}

Karikomi, Michinori ^{[1
]}

机构：

[1] Utsunomiya Univ, Grad Sch Engn, Dept Mat & Environm Chem, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 38期

关键词：

Bisphenols; Quinones; Helicenes; Ligands; COUPLING REACTIONS; ASYMMETRIC CATALYSIS; COMPLEXES; 2-NAPHTHOLS; BINAP; REAGENT; BINOL;

D O I：

10.1016/j.tetlet.2017.08.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new class of helical shaped bi-phenol (1,1'-bibenzo[c]phenanthrene-2,2'-diol; HEBPOL) type derivatives 2a-g were synthesized from quinone derivatives using the conventional 5% Pd-C catalytic reduction process. We obtained excellent yields for all of the 2a-g derivatives. The HEBPOLs were characterized by different analytical techniques including FTIR, H-1 NMR, C-13 NMR, MS and X-ray crystallography. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：3704 / 3707

页数：4

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