Preparation and characterization of L-cystine and L-cysteine intercalated layered double hydroxides

被引:35
|
作者
Wei, Min [1 ]
Guo, Jian [1 ]
Shi, Zhiyu [1 ]
Yuan, Qi [1 ]
Pu, Min [1 ]
Rao, Guoying [1 ]
Duan, Xue [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1007/s10853-006-1368-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
L-cystine and L-cysteine have been intercalated into magnesium-aluminum layered double hydroxide by the methods of coprecipitation and ion-exchange. The structure and composition of the intercalated materials have been characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and elemental analysis. For L-cysteine intercalated composites, two kinds of well-crystallized materials with different basal spacing were obtained, as a result of the different charge on an ion and orientation of the gallery anions. The schematic models of the intercalation structures were proposed. In addition, the thermal decomposition of L-cystine and L-cysteine intercalated LDHs has been investigated by means of thermogravimetry and differential thermal analysis (TG-DTA).
引用
收藏
页码:2684 / 2689
页数:6
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