Flexible electroactive PVDF/ZnO nanocomposite with high output power and current density

被引:22
|
作者
Chandran, Akash M. [1 ]
Varun, S. [1 ]
Mural, Prasanna Kumar S. [1 ]
机构
[1] Natl Inst Technol Calicut, Dept Chem Engn, Mat Chem & Polymer Technol Grp, Kozhikode 673601, Kerala, India
来源
POLYMER ENGINEERING AND SCIENCE | 2021年 / 61卷 / 06期
关键词
phase-inversion; piezoelectric nanogenerator; polymer nanocomposite; zinc oxide; beta-Phase; POLY(VINYLIDENE FLUORIDE) MEMBRANES; PIEZOELECTRIC NANOGENERATOR; CRYSTALLIZATION BEHAVIOR; BETA-POLYMORPH; DIELECTRIC-CONSTANT; PHASE INVERSION; GRAPHENE OXIDE; THIN-FILMS; COMPOSITES; ENERGY;
D O I
10.1002/pen.25704
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In the present study, a lightweight and flexible polyvinylidene fluoride (PVDF)/zinc oxide (ZnO) nanocomposite was prepared using a low-temperature phase-inversion process. The synergetic effect of low-temperature, phase-inversion, and the integration of ZnO nanoparticles primes on enhancing the electroactive polar beta-phase in the nanocomposite. The transformation of the electroactive phase and its quantification were carried out using Fourier-transform infrared spectroscopy and wide-angle X-ray diffraction. The PVDF/ZnO piezoelectric polymer nanocomposite was utilized for energy harvesting application that showed a better electromechanical response of ca. 69 V (peak to peak) at similar to 1.6 N, 250 mu W/cm(2) surface power density and 0.25 mA/cm(2) surface current density. The fabricated piezoelectric polymer nanocomposite is a possible candidate for superior energy scavenging applications for capturing human kinematics.
引用
收藏
页码:1829 / 1841
页数:13
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