A porphyrin-based microporous network polymer that acts as an efficient catalyst for cyclooctene and cyclohexane oxidation under mild conditions

被引：30

作者：

Antonangelo, Ariana R. ^{[1
]}

Bezzu, C. Grazia ^{[2
]}

Mughal, Sabeeha S. ^{[3
]}

Malewschik, Talita ^{[1
]}

McKeown, Neil B. ^{[2
]}

Nakagaki, Shirley ^{[1
]}

机构：

[1] Univ Fed Parana UFPR, Dept Quim, BR-81531990 Curitiba, Parana, Brazil

[2] Univ Edinburgh, EastChem Sch Chem, Edinburgh EH9 3FJ, Midlothian, Scotland

[3] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 99卷

关键词：

Porphyrins; Polymers of Intrinsic Microporosity (PIMs); Porous; Heterogeneous catalysis; Oxidation; METAL-ORGANIC FRAMEWORK; MANGANESE PORPHYRIN; INTRINSIC MICROPOROSITY; SELECTIVE OXIDATION; PHTHALOCYANINE; COMPLEXES;

D O I：

10.1016/j.catcom.2017.05.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The highly efficient dibenzodioxin-forming reaction between the (pentafluorophenyl)porphyrin manganese(III) (MnP) and hexahydroxytriptycene (HHT) provide a new microporous network polymer (P1), which demonstrated a large surface area (1080 m(2) g(-1)) and proved to be an efficient solid for heterogeneous catalysis for cyclooctene and cyclohexane oxidation under mild conditions and with high capacity of recovery and reuse in many catalytic cycles.

引用

页码：100 / 104

页数：5

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