Oxidation of pinane using zeolite encapsulated metal phthalocyanine catalysts

被引：0
|
作者：
Valente, AA [1 ]
Vital, J [1 ]
机构：
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, CQFB, Dept Quim, P-2825 Monte De Caparica, Portugal
来源：
HETEROGENEOUS CATALYSIS AND FINE CHEMICALS IV | 1997年 / 108卷
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxidation of cis-pinane by t-butyl hydroperoxide is catalysed by iron and cobalt phthalocyanines encapsulated in NaY zeolites. The main reaction product is 2-pinane hydroperoxide which in turn decomposes giving substituted cyclobutanes. In contrast to the reaction in homogeneous phase, products of oxidation on C3 and C4 are not observed.
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页码：461 / 468
页数：8
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