Disorder effects on heat transport properties of orientationally disordered crystals

被引:15
|
作者
Sharapova, I. V. [1 ]
Krivchikov, A. I. [1 ]
Korolyuk, O. A. [1 ]
Jezowski, A. [2 ]
Rovira-Esteva, M. [3 ]
Tamarit, J. Ll. [3 ]
Pardo, L. C. [3 ]
Ruiz-Martin, M. D. [3 ]
Bermejo, F. J. [4 ]
机构
[1] NAS Ukraine, B Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine
[2] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland
[3] Univ Politecn Cataluna, ETSEIB, Dept Fis & Engn Nucl, Grp Caracteritzacio Mat, E-08028 Barcelona, Catalonia, Spain
[4] Univ Basque Country, Dept Elect & Elect, CSIC, Bilbao 48080, Spain
关键词
TEMPERATURE THERMAL-CONDUCTIVITY; TUNNELING STATES; GLASS; DYNAMICS; PHONONS; MODES;
D O I
10.1103/PhysRevB.81.094205
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The thermal conductivity k(T) of the orientational glass state of 1,2-difluoro-1,1,2,2-tetrachloroethane (CFCl2-CFCl2, Freon 112) and cyanocyclohexane (C6H11CN) has been measured under equilibrium pressure within the temperature range 2-100 K. The results show that the soft-potential model is able to account for low-temperature data and, indeed, quantitative agreement of all data considered is found within this realm. The details beyond such temperatures are heavily dependent on chemical details and a large plateau is observed for Freon 112 which is rationalized in terms of resonant scattering of phonons by simple oscillators. Such a view is given additional support by the presence of a strong low-frequency feature in the generalized frequency spectrum of the former material as proven by inelastic neutron-scattering spectroscopy.
引用
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页数:6
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