The non-Gaussian tops and tails of diffusing boomerangs

被引:7
|
作者
Koens, Lyndon [1 ]
Lisicki, Maciej [1 ,2 ]
Lauga, Eric [1 ]
机构
[1] Univ Cambridge, Dept Appl Math & Theoret Phys, Cambridge, England
[2] Univ Warsaw, Fac Phys, Inst Theoret Phys, Warsaw, Poland
关键词
BROWNIAN-MOTION; HYDRODYNAMIC PROPERTIES; RIGID PARTICLES; DIMENSIONS; MOVEMENT; SHAPE;
D O I
10.1039/c6sm02649d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experiments involving the two-dimensional passive diffusion of colloidal boomerangs tracked off their centre of mobility have shown striking non-Gaussian tails in their probability distribution function [Chakrabarty et al., Soft Matter, 2016, 12, 4318]. This in turn can lead to anomalous diffusion characteristics, including mean drift. In this paper, we develop a general theoretical explanation for these measurements. The idea relies on calculating the two-dimensional probability densities at the centre of mobility of the particle, where all distributions are Gaussian, and then transforming them to a different reference point. Our model clearly captures the experimental results, without any fitting parameters, and demonstrates that the one-dimensional probability distributions may also exhibit strongly non-Gaussian tops. These results indicate that the choice of tracking point can cause a considerable departure from Gaussian statistics, potentially causing some common modelling techniques to fail.
引用
收藏
页码:2977 / 2982
页数:6
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