(E)-N′-(2-Hydroxybenzylidene)-2-(4-isobutylphenyl)propanohydrazide

被引:8
|
作者
Goh, Jia Hao [1 ]
Fun, Hoong-Kun [1 ]
Vinayaka, A. C. [2 ]
Kalluraya, B. [2 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Mangalore Univ, Dept Studies Chem, Mangalore 574199, India
关键词
X-RAY; HYDRAZONES; DIFFRACTION; HYDRAZIDE;
D O I
10.1107/S1600536809050971
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title hydrazide compound, C(20)H(24)N(2)O(2), exists in a trans configuration with respect to the acyclic C=N bond and an intramolecular O-H center dot center dot center dot N hydrogen bond generates an S(6) ring motif. The mean plane through the formohydrazide unit is essentially planar [maximum deviation = 0.025 (2) angstrom], and forms dihedral angles of 24.45 (16) and 87.14 (16)degrees with the two benzene rings. In the crystal structure, intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link neighbouring molecules into extended chains along the c axis, which incorporate R(2)(2)(16) ring motifs. An intermolecular C-H center dot center dot center dot pi interaction is also observed.
引用
收藏
页码:O24 / U1306
页数:11
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