The unimolecular elimination kinetics of benzaldoxime in the gas phase

被引：2
|
作者：
Julio, Libia L.
Herize, Armando
Tosta, Maria
Dominguez, Rosa M.
Lafont, Jennifer
Chuchani, Gabriel
机构：
[1] Inst Venezolano Invest Cient, Ctr Quim, Caracas 1020A, Venezuela
[2] Univ Cordoba, Dept Quim, Monteria, Colombia
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 2007年 / 39卷 / 03期
关键词：
D O I：
10.1002/kin.20222
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of the gas-phase elimination of benzaldoxime was determined in a static reaction system over the temperature and pressure range 350 degrees C-400 degrees C and 56-140 Torr, respectively. The products obtained were benzonitrile and water. The reaction was found to be homogeneous, unimolecular, and tend to obey a first-order rate law. The observed rate coefficient is represented by the following Arrhenius equation
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收藏
页码：145 / 147
页数：3
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