Densities, viscosities, and refractive indices of binary liquid mixtures of hexane, decane, hexadecane, and squalane with benzene at 298.15 K

被引:53
|
作者
Lal, K [1 ]
Tripathi, N [1 ]
Dubey, GP [1 ]
机构
[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India
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关键词
D O I
10.1021/je000103x
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities, rho, viscosities, eta, and refractive indices, n(D), for binary mixtures of hexane, decane, hexadecane, and squalane with benzene were measured over the whole composition range at 298.15 K and atmospheric pressure. The excess molar volumes, V-m(E), and viscosity deviations, delta eta, were calculated from experimental measurements. These result were further fitted to the Redlich-Kister equation to estimate the binary coefficients and standard errors. The effects of chain length and branching of alkanes on V-m(E) and delta eta values have been discussed.
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页码:961 / 964
页数:4
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