Kinetics and mechanism of copper interaction with gaseous sulfur

被引:0
|
作者
Tereshkova, SG [1 ]
机构
[1] Byelarussian Acad Sci, Inst Gen & Inorgan Chem, Minsk, BELARUS
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The kinetics of the formation of dense and porous sulfide layers of scale on copper and the kinetics of sulfur evaporation from the inner surface of the dense layer were studied. The mechanism of the process was established using the radioactive isotope S-35. Partial reversibility of the solid-phase reaction was observed. The causes leading to the formation of a nonstoichiometric sulfide were discussed.
引用
收藏
页码:217 / 220
页数:4
相关论文
共 50 条
  • [1] Kinetics and Mechanism of Copper Interaction with Gaseous Sulfur
    Inst. of Gen. and Inorg. Chemistry, Belarus Academy of Sciences, Minsk, Belarus
    Kinet. Catal., 2 (217-220):
  • [2] KINETICS OF INTERACTION OF IRON, COPPER, LEAD AND ZINC SULFIDES WITH GASEOUS REDUCTANTS
    CHIZHIKO.DM
    RUMYANTS.YV
    GOLSHTEI.TB
    PAVLYUCH.NM
    DANILCHE.VA
    IMENITOV, AV
    AVAKYAN, GA
    DOKLADY AKADEMII NAUK SSSR, 1974, 215 (02): : 406 - 407
  • [3] Reaction between gaseous sulfur dioxide and solid calcium oxide - Mechanism and kinetics
    Allen, D
    Hayhurst, AN
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (07): : 1227 - 1238
  • [4] Kinetics of the sulfidation of chalcopyrite with gaseous sulfur
    R. Padilla
    E. Olivares
    M. C. Ruiz
    H. Y. Sohn
    Metallurgical and Materials Transactions B, 2003, 34 : 61 - 68
  • [5] Kinetics of the sulfidation of chalcopyrite with gaseous sulfur
    Padilla, R
    Olivares, E
    Ruiz, MC
    Sohn, HY
    METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2003, 34 (01): : 61 - 68
  • [6] ON THE ROLE OF GASEOUS-PHASE IN KINETICS OF INTERACTION OF COPPER WITH NITRIC-ACID
    GUMNITSKY, YM
    MALLIK, S
    UKRAINSKII KHIMICHESKII ZHURNAL, 1989, 55 (05): : 473 - 476
  • [7] KINETICS OF COMBUSTION OF GASEOUS SULFUR-COMPOUNDS
    CULLIS, CF
    MULCAHY, MFR
    COMBUSTION AND FLAME, 1972, 18 (02) : 225 - &
  • [8] STUDIES ON KINETICS AND MECHANISM OF REACTION OF SULFUR-DIOXIDE AND NITROGEN-OXIDES WITH GASEOUS AMMONIA
    HABER, J
    PAWLIKOW.J
    POMIANOW.A
    NAJBAR, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 404 (03): : 284 - 294
  • [9] Kinetics and mechanism of sulfamic acid interaction with copper, zinc and cobalt bicarbonates
    Maksin, V.I.
    Standrichuk, O.Z.
    2001, Naukova dumka (23):
  • [10] Kinetics and Mechanism of Hydrothermal Interaction Between Sphalerite and Copper Sulfate.
    Naboichenko, S.S.
    Neustroyev, V.I.
    Pinigin, V.K.
    Khudyakov, I.F.
    Izvestiya Vysshikh Uchebnykh Zavedenij. Tsvetnaya Metallurgiya, 1979, (05): : 18 - 23