Nucleophilic addition to 3-methyl-1-(4-nitrophenyl)-2-phenyl-4,5-dihydroimidazolium iodide

被引：8
|
作者：
Xia, CH [1 ]
Tang, YQ [1 ]
Zhou, PW [1 ]
机构：
[1] Shanxi Univ, Inst Mol Sci, Taiyuan, Peoples R China
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 2000年 / 37卷 / 05期
关键词：
D O I：
10.1002/jhet.5570370552
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reactions of the 1,2-diaryl 4,5-dihydroimidazolium, represented by 3-methyl-1-(4-nitrophenyl)-2-phenyl-4,5-dihydroimidazolium iodide 1, with ethylenediamine afforded a benzylidyne unit transferred product, 2-phenyl-2-imidazoline 2; a ring-opened adduct 4 was produced when excess ethylenediamine was used. Reactions of 1 with hydroxylamine, malononitrile, and nitromethane anions produced ring-opened products, 5, 7, and 8 respectively.
引用
收藏
页码：1329 / 1331
页数：3
相关论文
共 50 条
  • [1] 1,2-dimethyl-3-(2-nitrophenyl)-4,5-dihydroimidazolium iodide
    Li, DH
    Hao, JS
    Huo, FJ
    Huang, SP
    Zhang, YB
    Xia, CZ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : O844 - O845
  • [2] Nucleophilic addition to substituted 1H-4,5-dihydroimidazolium salts
    Salerno, A
    Ceriani, V
    Perillo, IA
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1997, 34 (03) : 709 - 716
  • [3] Nucleophilic addition to 1,2-dimethyl-3-arylsulfonyl-4,5-dihydroimidazolium iodides
    Xia, CH
    Chen, JX
    Wang, HX
    Kang, CM
    Zhao, BJ
    Ni, YP
    Zhou, PW
    SYNTHETIC COMMUNICATIONS, 2002, 32 (19) : 2979 - 2984
  • [4] Nucleophilic addition to 1,2-dimethyl-3-arylsulfonyl-4,5-dihydroimidazolium iodides.
    Xia, CZ
    Chen, JX
    Wang, HX
    Kang, CM
    Zhao, BJ
    Zhou, PW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U135 - U135
  • [5] Reactions of 2,3-diaryl-1-methyl-4,5-dihydroimidazolium iodides with nucleophilic reagents
    Xia, CZ
    Hao, JS
    Tang, YQ
    Ni, YP
    Zhou, PW
    SYNTHETIC COMMUNICATIONS, 2002, 32 (09) : 1457 - 1464
  • [6] 3-(4-methoxyphenyl)-1,2-dimethyl-4,5-dihydroimidazolium iodide
    Li, DH
    Hao, JS
    Tong, HB
    Huang, SP
    Zhang, YB
    Xia, CZ
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O855 - O856
  • [7] 5-(2-Furyl)-3-methyl-1-(4-nitrophenyl)-2-pyrazoline
    Yin, Zhi-Gang
    Xu, Pei-Yuan
    Qian, Heng-Yu
    Zhou, Na
    Liu, Sheng-Min
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5508 - O5509
  • [8] 3-Methyl-1-(3-nitrophenyl)-5-phenyl-4,5-dihydro-1H-pyrazole
    Chen, Jun-qiang
    Li, He-ping
    Huang, Chang-shan
    Wu, Jin-ying
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2156 - U2048
  • [9] Methyl 2-{[(3-methyl-5-oxo-1-phenyl4,5-dihydro-1H-pyrazol-4-ylidene)(4-nitrophenyl) methyl] amino}-3-phenylpropanoate
    Zhang, Xin
    Sun, Chen
    Li, Fei-Ran
    Zhang, Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1062 - +
  • [10] 5-(2-Furyl)-3-methyl-1-(3-nitrophenyl)-4,5-dihydro-1H-pyrazole
    Chen, Jun-qiang
    Li, He-ping
    Huang, Chang-shan
    Wu, Jin-ying
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2147 - U1969
12345