Two Tetranuclear Zinc(II) Coordination Polymers Based on 3,5-Bis(2-carboxylphenoxy)benzoic Acid with Highly Selective Sensing of Nitrobenzene

被引：0
|
作者：
Fang Ke-Gong [1 ]
Zhao Qian-Nan [2 ]
Li Miao-Miao [2 ]
Hu Tuo-Ping [1 ,2 ]
机构：
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
[2] North Univ China, Coll Sci, Dept Chem, Taiyuan 030051, Shanxi, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 05期
基金：
中国国家自然科学基金;
关键词：
3,5-bis(2-carboxylphenoxy)benzoic acid; tetranuclear cluster; zinc; luminscence; METAL-ORGANIC FRAMEWORKS; STRUCTURAL DIVERSITY; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; NITRO EXPLOSIVES; LIGAND; LUMINESCENCE; SERIES; DERIVATIVES; COMPLEXES;
D O I：
10.14102/j.cnki.0254-5861.2011-1841
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel zinc(II) coordination polymers, [Zn-2(BCB)(CH3OH)(mu(3)-OH)](n) (1) and {[Zn-2(BCB)(mu(3)-OH)(H2O)(2)]center dot CH3OH}(n) (2), have been constructed from 3,5-bis(2-carboxylphenoxy)benzoic acid (H3BCB) and characterized by elemental analysis (EA), IR, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. Structural analysis reveals that complexes 1 and 2 are both 1D polymeric chains with unprecedented tetranuclear {Zn-4(COO)(4)(mu(3)-OH)(2)} clusters, which were further expanded into a 2D structure. Fluorescence measurements show that 1 and 2 have highly selective and sensitive detection of nitrobenzene.
引用
收藏
页码：787 / 795
页数：9
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