Synthesis and characterization of yttrium complexes containing a tridentate linked amido-cyclopentadienyl ligand

被引：30
|
作者：
Hultzsch, KC [1 ]
Spaniol, TP [1 ]
Okuda, J [1 ]
机构：
[1] Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 03期
关键词：
D O I：
10.1021/om970701d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of dilithium salts of the tridentate linked amido-cyclopentadienyl ligands Li-2(C5Me4SiMe2NCH2CH2X) (X = OMe, NMe2, CH2OMe) with [Y(o-C6H4CH2NMe2)Cl-2(LiCl)(THF)(4)] and Y(eta(5)-C5H5)Cl-2(THF)(3) give chloro-bridged ate complexes of the type [Li(THF)][Y(eta(5):eta(1)-C5Me4SiMe2NCH2CH2X) (R)Cl], where R = o-C6H4CH2NMe2, eta(5)-C5H5.
引用
收藏
页码：485 / 488
页数：4
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