Total synthesis of (±)-elegansidiol, (±)-farnesiferol B, and (±)-farnesiferol D

被引：9
|
作者：
Yadav, Jhillu Singh [1 ]
Satyanarayana, Kamani [1 ]
Sreedhar, Pamu [1 ]
Srihari, Pabbaraja [1 ]
Shaik, Thokhir Basha
Kalivendi, Shasi Vardhan
机构：
[1] CSIR, Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500607, Andhra Pradesh, India
来源：
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 2010年 / 20卷 / 12期
关键词：
Terpene; Intermolecular Diels-Alder; Reduction; Wittig; Metathesis; ALKYL ALPHA; BETA-UNSATURATED KETONES; ACHILLEA-ODORATA L; RELATIVE STEREOCHEMISTRY; TRITERPENE SKELETON; CUPRATE REAGENTS; (-)-ELEGANSIDIOL; SESQUITERPENOIDS; TRANSFORMATIONS; ELEGANSIDIOL; TERPENOIDS;
D O I：
10.1016/j.bmcl.2010.04.030
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
The racemic total synthesis of elegansidiol, farnesiferol B, and farnesiferol D has been obtained following a Diels-Alder approach. Gillman addition, cross metathesis reaction are the other key steps involved in the target synthesis. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3814 / 3817
页数：4
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