The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly

被引:16
|
作者
Pedrido, Rosa [1 ]
Vazquez Lopez, Miguel [1 ]
Sorace, Lorenzo [2 ,3 ]
Gonzalez-Noya, Ana M. [4 ]
Cwiklinska, Magdalena [1 ]
Suarez-Gomez, Vanesa [1 ]
Zaragoza, Guillermo [5 ]
Bermejo, Manuel R. [1 ]
机构
[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Inorgan, Santiago De Compostela 15782, Spain
[2] Univ Florence, Lab Mol Magnetism, Dipartimento Chim Ugo Schiff, I-50019 Sesto Fiorentino, Fi, Italy
[3] Univ Florence, UdR INSTM, I-50019 Sesto Fiorentino, Fi, Italy
[4] Univ Santiago de Compostela, Fac Ciencias, Dept Quim Inorgan, Lugo 27002, Spain
[5] Univ Santiago de Compostela, Unidad Difracc Rayos X, Santiago De Compostela 15782, Spain
关键词
ELECTROCHEMICAL SYNTHESIS; COMPLEXES; CRYSTAL; ROUTE;
D O I
10.1039/c0cc00338g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A method to modulate the strength of the superexchange coupling interaction in dinuclear helical assemblies based on the coordination preferences of the metal centres is described.
引用
收藏
页码:4797 / 4799
页数:3
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