Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures

被引：3
|
作者：
Cherkasova, E. V. [1 ]
Pervukhina, N. V. [2 ]
Kuratieva, N. V. [2 ,4 ]
Bagryanskaya, I. Yu. [3 ,4 ]
Cherkasova, T. G. [1 ]
机构：
[1] TF Gorbachev Kuzbass State Tech Univ, Kemerovo 650000, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
[4] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 05期
关键词：
D O I：
10.1134/S003602361805011X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Double ionic complexes [M(C5H5NCOO)(3)(H2O)(2)][Cr(NCS)(6)] center dot nH(2)O, where M = Eu (I), n = 1.15; Dy (II), Er (III), n = 1.5; M = Yb (IV), n = 2, have been synthesized by the reaction between M(NO3)(3), M = Eu, Dy, Er, Yb, K-3[Cr(NCS)(6)], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals of complexes I-IV are monoclinic, space group P2(1)/n, Z = 4; a = 9.5358(2) , b = 25.4871(5) , c = 15.4303(4) , beta = 105.513(1)A degrees, V = 3613.6(1) (3), rho(calcd) = 1.799 g/cm(3) for I, a = 9.5901(5) , b = 25.8599(15) , c = 15.6316(9) , beta = 106.829(2)A degrees, V = 3710.6(4) (3), rho(calcd) = 1.782 g/cm(3) for II, a = 9.5640(3) , b = 25.8936(11) , c = 15.6498(7) , beta = 106.895(2)A degrees, V = 3708.3(3) (3), rho(calcd) = 1.791 g/cm(3) for III, and a = 9.5049(2) , b = 25.6378(4) , c = 15.5120(3) , beta = 106.934(1)A degrees, V = 3616.1(1) (3), rho(calcd) = 1.864 g/cm(3) for IV.
引用
收藏
页码：626 / 630
页数：5
相关论文
共 50 条
  • [1] Hexa(isothiocyanato)chromates(III) of Some Yttrium Group Lanthanide(III) and Europium Complexes with Nicotinic Acid: Synthesis and Crystal Structures
    E. V. Cherkasova
    N. V. Pervukhina
    N. V. Kuratieva
    I. Yu. Bagryanskaya
    T. G. Cherkasova
    Russian Journal of Inorganic Chemistry, 2018, 63 : 626 - 630
  • [2] Synthesis, crystal structure, and structural features of hexa(isothiocyanate)chromates(III) of lanthanum(III) and neodymium(III) complexes with nicotinic acid
    Cherkasova, E. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Cherkasova, T. G.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (09) : 1040 - 1046
  • [3] Synthesis, crystal structure, and structural features of hexa(isothiocyanate)chromates(III) of lanthanum(III) and neodymium(III) complexes with nicotinic acid
    E. V. Cherkasova
    E. V. Peresypkina
    A. V. Virovets
    T. G. Cherkasova
    Russian Journal of Inorganic Chemistry, 2013, 58 : 1040 - 1046
  • [4] Synthesis and Features of Crystal Structure of Scandium Hexa(isothiocyanato)chromate(III) Complex with Nicotinic Acid
    Cherkasova, E. V.
    Pervukhina, N. V.
    Kuratieva, N. V.
    Cherkasova, T. G.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (06) : 776 - 780
  • [5] Synthesis and Features of Crystal Structure of Scandium Hexa(isothiocyanato)chromate(III) Complex with Nicotinic Acid
    E. V. Cherkasova
    N. V. Pervukhina
    N. V. Kuratieva
    T. G. Cherkasova
    Russian Journal of Inorganic Chemistry, 2018, 63 : 776 - 780
  • [6] STRUCTURAL STUDIES OF BRIDGED LANTHANIDE(III) COMPLEXES - DIAQUOTRI(NICOTINIC ACID)HOLMIUM(III) HEXA(ISOTHIOCYANATO)CHROMATE(III) DIHYDRATE AND DIAQUOTRIS(ISONICOTINATO)LANTHANUM(III)
    KAY, J
    GLICK, MD
    MOORE, JW
    INORGANIC CHEMISTRY, 1972, 11 (11) : 2818 - &
  • [7] Structural types of octa(ɛ-caprolactam)-lanthanide(III) hexa(isothiocyanato)chromates(III). Phase transition with reversible twinning
    A. V. Virovets
    E. V. Peresypkina
    E. V. Cherkasova
    T. G. Cherkasova
    N. V. Podberezskaya
    Journal of Structural Chemistry, 2009, 50 : 137 - 148
  • [8] Structural types of octa(E⟩-caprolactam)-lanthanide(III) hexa(isothiocyanato)chromates(III). Phase transition with reversible twinning
    Virovets, A. V.
    Peresypkina, E. V.
    Cherkasova, E. V.
    Cherkasova, T. G.
    Podberezskaya, N. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (01) : 137 - 148
  • [9] Hexa(isothiocyanato)chromates(III) of zirconium(IV) complexes with epsilon-caprolactam and amidopyrine
    Cherkasova, TG
    Tatarinova, ES
    ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (09): : 1515 - 1517
  • [10] Hexa(isothiocyanato)chromates(III) of Zirconium(IV) Complexes with curly upsilon-Caprolactam and Amidopyrine
    Cherkasova, T. G.
    Tatarinova, E. S.
    Russian Journal of Inorganic Chemistry, 1996, 41 (09)
12345