Phase equilibria in the YbTe-Sb2Te3-Te system

被引:0
|
作者
Aliev, Ziya S. [1 ,3 ]
Ibadova, Gulnara I. [1 ]
Tedenac, Jean-Claude [4 ]
Babanly, Mahammad B. [1 ,2 ]
机构
[1] Baku State Univ, Gen & Inorgan Chem Dept, Baku, Azerbaijan
[2] Azerbaijan Natl Acad Sci, Inst Catalysis & Inorgan Chem, Baku, Azerbaijan
[3] Azerbaijan Natl Acad Sci, Inst Phys, Baku, Azerbaijan
[4] Univ Montpellier 2, ICGM, UMR 5253, Montpellier, France
关键词
Quasi-binary system; Phase diagram; Invariant eutectic; Ytterbium telluride; Antimony telluride; TOPOLOGICAL INSULATORS; STATES;
D O I
10.1016/j.jallcom.2014.08.102
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The phase equilibria in the YbTe-Sb2Te3-Te system were investigated by means of differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscope with energy dispersive analysis (SEM-EDS) techniques. Two isopleth sections and liquidus surface projection were constructed. The primary crystallization fields of phases, the character and temperatures of the invariant and monovariant processes were determined. No new ternary compound was found in this system and moreover, known ternary compounds YbSb2Te4 and YbSb4Te7 were not confirmed. The newly determined phase equilibria in this sub-system will provide important information for the future construction of self-consistent phase diagram of the ternary Yb-Sb-Te system in the entire concentration range. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:167 / 171
页数:5
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