Reactions of thioamides with metal carboxylates in organic media

被引：28

作者：

Avalos, M ^{[1
]}

Babiano, R ^{[1
]}

Cintas, P ^{[1
]}

Duran, CJ ^{[1
]}

Higes, FJ ^{[1
]}

Jimenez, JL ^{[1
]}

Lopez, I ^{[1
]}

Palacios, JC ^{[1
]}

机构：

[1] UNIV EXTREMADURA,FAC CIENCIAS,DEPT QUIM INORGAN,E-06071 BADAJOZ,SPAIN

来源：

TETRAHEDRON | 1997年 / 53卷 / 42期

关键词：

amides; imides; metal carboxylates; nitriles; thioamides;

D O I：

10.1016/S0040-4020(97)00938-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of thioamides with metal carboxylates in organic solvents are described. These processes enable the selective preparation of nitriles, imides or amides depending on the substitution pattern of the starting material. Mechanistic hypotheses supported by experimental evidences, including the unequivocal synthesis of bis(thioacetanilide)mercury(II) as a key reaction intermediate, are also proposed. (C) 1997 Elsevier Science Ltd.

引用

页码：14463 / 14480

页数：18

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