Daucus carota and baker's yeast mediated bio-reduction of prochiral ketones

被引：47

作者：

Yadav, Jhillu S. ^{[1
]}

Reddy, Garudammagari S. K. K. ^{[1
]}

Sabitha, Gowravaram ^{[1
]}

Krishna, Avvaru D. ^{[1
]}

Prasad, Attaluri R. ^{[1
]}

Hafeez-U-R-Rahaman ^{[1
]}

Rao, Katta Vishwaswar ^{[1
]}

Rao, Adari Bhaskar ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON-ASYMMETRY | 2007年 / 18卷 / 06期

关键词：

D O I：

10.1016/j.tetasy.2007.03.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stereoselective reduction of prochiral ketones to the corresponding alcohols using biocatalysts has attracted much attention, from the viewpoint of green chemistry. Asymmetric reduction of indanone, tetralone and hydroxyl trimonoterpene ketones to the corresponding enantiomerically pure (S)-alcohols, using Daucus carota plant homogenate and fermented baker's yeast cells, is described. The present study illustrates the broad substrate selectivity of the dehydrogenase enzymes present in the D. carota in the synthesis of a wide range of chiral secondary alcohols of biological importance. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：717 / 723

页数：7

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