Trimethylsilyl Pseudohalide Adducts of GaCl3 and B(C6F5)3

被引：4
|
作者：
Blaesing, Kevin [1 ]
Bresien, Jonas [1 ]
Maurer, Steffen [1 ]
Schulz, Axel [1 ,2 ]
Villinger, Alexander [1 ]
机构：
[1] Univ Rostock, Inst Chem, Anorgan Chem, A Einstein Str 3a, D-18059 Rostock, Germany
[2] Univ Rostock, Mat Design, Leibniz Inst Katalyse, A Einstein Str 29a, D-18059 Rostock, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 2021卷 / 20期
关键词：
Adducts; Azides; Cyanates; Cyanides; Pseudohalogens; Rhodanides; ROUTE; CN; DERIVATIVES; REACTIVITY; CHEMISTRY; CYCLOADDITION; COORDINATION; DIFFRACTION; COMPLEXES; REAGENTS;
D O I：
10.1002/ejic.202100237
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Me3Si-X (X=CN, N-3, OCN, and SCN) was treated with the Lewis acids GaCl3 and B(C6F5)(3) in toluene yielding the desired adducts Me3Si-X -> GaCl3 and Me3Si-X -> B(C6F5)(3). All synthesized adducts were isolated and completely characterized including single crystal structure elucidations. The different structures, thermodynamics of formation and charge transfer effects are discussed on the basis of experimental and theoretical data.
引用
收藏
页码：1913 / 1920
页数：8
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