Synthesis and Characterization of N-(2,2-Diphenylacetyl)-N′-Substituted Thiourea Derivatives: The Crystal Structure of N-(2,2-Diphenylacetyl)-N′-(4-chloro phenyl)-thiourea

被引：13

作者：

Mansuroglu, Demet Sezgin ^{[1
]}

Arslan, Hakan ^{[1
]}

VanDerveer, Don ^{[2
]}

Binzet, Guen ^{[3
]}

机构：

[1] Mersin Univ, Dept Chem, Fac Pharm, TR-33169 Mersin, Turkey

[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

[3] Mersin Univ, Dept Chem, Fac Arts & Sci, TR-33169 Mersin, Turkey

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 12期

关键词：

Pseudo-six-membered ring; single crystal structure determination; synthesis; thiourea; VIBRATIONAL-SPECTRA; MOLECULAR-STRUCTURE; THERMAL-BEHAVIOR; METAL-COMPLEXES; HARTREE-FOCK; X-RAY; BENZOYL; LIGANDS; NI(II); COPPER(II);

D O I：

10.1080/10426500902979743

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new N-(2,2-diphenylacetyl)-N'-substituted thiourea derivatives (1-9) have been prepared and characterized by elemental analyses, IR and H-1 NMR spectroscopy. N-(2,2-diphenylacetyl)-N'-(4-chlorophenyl)-thiourea was also characterized by a single crystal X-ray diffraction study. The compound crystallizes in the monoclinic space group P2(1)/c with Z = 4 and a = 9.6551(19) angstrom, b = 20.060(4) angstrom, c = 9.894(2) angstrom, beta = 104.29(3)degrees. The molecular conformation of the compound is stabilized by an intramolecular (N1-H1 center dot center dot center dot O1) hydrogen bond that forms a pseudo-six-membered ring.

引用

页码：3221 / 3230

页数：10

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